When washing my hands, I was always told to use warm soapy water.

However, is there any chemical or biological reason why warm soapy water is more effective to cold soapy water when trying to sanitise your hands?

For example, a reason given for using warm water was that it opens your pores.

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I was told the same thing, the reason being, it opens your pores. Not sure if thats true, but thats what I was told. – John Isaacks Apr 26 '11 at 18:57
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Superior in what way? That it cleans better? – Sklivvz Apr 26 '11 at 18:57
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I was told in Red Cross training that the #1 factor in determining the effectiveness of hand washing is the friction. That's why surgeons scrub and scrub and scrub. – Apreche Apr 27 '11 at 11:37
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Of course, those natural oils also protect your hands during the winter, so if warm water removes them more effectively, it means you're more likely to get cracked and bleeding hands in cold weather. – Kyralessa Apr 27 '11 at 13:35
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btw, pores don't open/close (Source) – Oliver_C Apr 27 '11 at 15:48
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4 Answers

up vote 27 down vote accepted

According to

Hot Water for Handwashing - Where is the Proof?

The initial experiment involved testing with bland non-antimicrobial soap at 5 temperatures from 4.4°C (40°F) to 49°C (120°F). Independent of soil or bacterial type (resident or transient) there was no significant difference in efficacy attributed to water temperature.

[...]

In the second experiment antimicrobial soaps were used having different antimicrobial active ingredients, at each of two water temperatures, 29.5°C (85°F) and 43°C (110°F).

In this experiment, even though slightly higher efficacy was seen with antimicrobial soaps at higher temperatures, overall, there was no statistical difference in efficacy ... at the two water temperatures.

Concomitant to the increase in efficacy at higher temperatures was a consistent trend for increases in measures of skin damage, such as skin moisture content, transepidermal water loss and erythema. This was also found not to be statistically significant.

[...]

As has been shown by many previous researchers, overall handwashing effectiveness is more dependent on the vigorousness of execution than details such as the type of soap, the length of handwash or in this case water temperature.

For the complete text of the paper go here (it references more than 50 publications).

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It is to do with the surface tension of the water. The hotter the water the lower the surface tension hence the easier it is to wash dirt away (obviously you still need to scrub your hands, but as the surface tension is lower dirt should come away easier).

To quote a physics site:

The surface tension of water is 72 dynes/cm at 25°C . It would take a force of 72 dynes to break a surface film of water 1 cm long. The surface tension of water decreases significantly with temperature as shown in the graph. The surface tension arises from the polar nature of the water molecule. Hot water is a better cleaning agent because the lower surface tension makes it a better "wetting agent" to get into pores and fissures rather than bridging them with surface tension. Soaps and detergents further lower the surface tension.

enter image description here

EDIT

I should probably also mention that soap reduces the surface tension a lot more than heating the water will. (Source) Unfortunately I don't have a graph for this.

EDIT

Added a link to the patent for detergents to show that the point of detergents is to reduce the surface tension (Page 4) to improve the wetting ability of water and hence improve the washing efficiency (Page 5).

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This doesn't really make sense. How much of cleaning relies upon "getting into pores and fissures"? Skin, unless extremely oily, is not highly hydrophobic, and if it is extremely oily, the pores and fissures are full of oil. Seems to me that something else is going on. – Rex Kerr Apr 27 '11 at 14:37
Well looking at my hands I can see lots of fissures (Fingerprints, various lines, the odd scar, etc.) If I look close enough I can see skin pores as well. What the above is basically saying is that the surface tension of the water means it bridges across these imperfections in your skin rather than going into them to wash the dirt out. Lowering the surface tension allows the water to penetrate the fissures easier. You can either lower the surface tension by heating water, using soap, or both. – Ardesco Apr 27 '11 at 14:48
@Ardesco: Try putting a cold drop of water on your finger. Do you see bubbles trapped in your fingerprints? – Rex Kerr Apr 27 '11 at 14:52
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@Ardesco - Surface tension is a property of the self-interaction of water (or whatever solution you have). Surface tension causes weightless droplets in a vacuum to form into spheres. This is related to but not the same thing as as entrapment of dirt and oils in micelles, or the solubility of hydrophobic compounds in water (see en.wikipedia.org/wiki/Surfactant for example). Glass-finger contact is a red herring since both are nominally solids; one needs gas or liquid to fill in the spaces. Check out en.wikipedia.org/wiki/Hydrophobe and the Cassie-Baxter state. – Rex Kerr Apr 27 '11 at 17:39
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Beware: that graph is exaggerating. The graph appears to show that surface tension halves with increasing heat, but if you read the numbers it's only decreasing from about 74 to about 68. – ChrisW Jun 7 '11 at 12:26
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A recent scientific study showed that cold water works just as well. This is not the most recent study, but here is an article from The New York Times:

In a 2005 report in the Journal of Occupational and Environmental Medicine, scientists with the Joint Bank Group/Fund Health Services Department pointed out that in studies in which subjects had their hands contaminated, and then were instructed to wash and rinse with soap for 25 seconds using water with temperatures ranging from 40 degrees Fahrenheit to 120 degrees, the various temperatures had “no effect on transient or resident bacterial reduction.”

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However, is there any chemical or biological reason why warm soapy water is more effective to cold soapy water when trying to sanitise your hands?

Soap may dissolve better in warm water than cold (this is perhaps especially true of the soap your grandmother used to use, when your mum was being taught how to wash her hands).

People may do a longer/more thorough job of washing their hands when the water is warm (luxuriating the warm water all over their hands and between their fingers etc, instead of removing their hand from the cold water asap).

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I haven't found a reference to the fact that some soaps dissolve better at warmer temperatures ... I think this is a well-known factoid though, not controversial. – ChrisW Jun 7 '11 at 13:20
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